曹龙生，男，中国科学技术大学特任教授（独立PI），国家高层次青年人才（海外）。1988年出生于河北唐山，2011年于中国石油大学（北京）获得工学学士学位，2018博士毕业于中国科学院大连化学物理研究所，2018-2021在美国马里兰大学从事博士后研究，2022-2023在中国科学院大连化学物理研究所历任副研究员/研究员，2023年5月加入中国科学技术大学苏州高等研究院/化学与材料科学学院。主要研究内容包括仿生超流动、二次电池、电解水关键材料与技术，研究涉及电化学/工程、物理化学、纳米技术等多个化工/化学分支学科的交叉结合。相关研究工作相继发表在Nature Nanotech.（1篇）、Angew. Chem. Int. （3篇）、JACS（1篇）、Chem（1篇）、Nature Com.（1篇）、Nano Energy（1篇）等国际重要刊物上20余篇。申请中国专利16项，授权5项。

课题组欢迎本科生、硕士生、博士生、博士后加盟！

电子邮箱：caolsh@ustc.edu.cn

联系地址：中国科学技术大学苏州高等研究院(仁爱路166号)亲民楼313

主要研究方向

1）仿生超流动机制及应用；

2）仿生电解质及水系二次电池应用；

3）仿生电极材料及海水电解应用。

重要科研获奖情况

张大煜青年学者

Topsoe-DICP博士生奖学金

学术论文及著作

(1) Li, D.^*; Yu, Y.; Zhao, W.; Wang, F.; Su, Y.^*; Cao, L.^* Rechargeable Zinc-Water Battery for Sustainable Hydrogen Generation. Nano Energy 2024, 109806.

(2) Wang, M.; Cao, L.^*; Liu, Z.; Yang, W.; Sun, S.; Hou, M.^*; Shao, Z.^* Sulfur dioxide-resistant platinum-based intermetallic nanocatalysts encaged by porous nitrogen-doped carbon for oxygen reduction reaction. Chemical Engineering Journal 2024, 152162.

(3) Ma, L.; Pollard, T. P.; Schroeder, M. A.; Luo, C.; Zhang, Y.; Pastel, G.; Cao, L.; Zhang, J.; Shipitsyn, V.; Yao, Y. Engineering a zinc anode interphasial chemistry for acidic, alkaline and non-aqueous electrolytes. Energy & Environmental Science 2024, 17 (7), 2468-2479.

(4) Liu, Z.; Cao, L.^*; Wang, M.; Zhao, Y.; Hou, M.; Shao, Z.^* A robust Ni single-atom catalyst for industrial current and exceptional selectivity in electrochemical CO 2 reduction to CO. Journal of Materials Chemistry A 2024, 12 (14), 8331-8339.

(5) Huang, H.; Chen, T.; Fang, D.; Cao, L.^*; Wang, G.; Hao, J.; Shao, Z.^* Modulation in the electronic structure of Ir-rich shell on AuIr solid solution as OER electrocatalyst for PEM electrolyzer. Journal of Applied Electrochemistry 2024, 1-11.

(6) Huang, H.; Cao, L.^*; Fang, D.; Yu, H.; Shao, Z.^* Stable hydrogen evolution catalysis: Nitrogen-carbon-stabilized platinum on a microporous carbon-based framework. Journal of Electroanalytical Chemistry 2024, 952, 117985.

(7) Guo, Q.; Yuan, R.; Zhao, Y.; Yu, Y.; Fu, J.^*; Cao, L.^* Performance of Nitrogen‐Doped Carbon Nanoparticles Carrying FeNiCu as Bifunctional Electrocatalyst for Rechargeable Zinc‐Air Battery. Small 2024, 2400830.

(8) Zhu, J.; Li, P.; Wang, G.^*; Cao, L.^*; Liu, S. Design strategy for high-performance bifunctional electrode materials with heterogeneous structures formed by hydrothermal sulfur etching. Journal of Colloid and Interface Science 2023, 633, 608-618.

(9) Zhao, Z.^*; Tang, S.; Liu, Z.; Cao, L.; Cheng, M.; Shao, Z.^* Efficient and stable heterostructured air electrode for solid oxide steam electrolysis. International Journal of Hydrogen Energy 2023, 48 (15), 5764-5773.

(10) Luo, W.; Cao, L.^*; Hou, M.^*; Zhou, Y.; Ren, Z.; Geng, J.; Shao, Z.^* MOF-Based Co and Mn Embedded in Nitrogen-Doped Microporous Carbon as an Efficient Catalyst for Oxygen Reduction Reaction in Anion Exchange Membrane Fuel Cell. International Journal of Energy Research 2023, 2023.

(11) Luo, W.; Cao, L.^*; Hou, M.^*; Ren, Z.; Xie, F.; Shao, Z.^* N-doped porous carbon encapsulated Fe and Ni bimetal derived from MOFs as efficient oxygen reduction reaction catalysts for anion exchange membrane fuel cell. Journal of Electroanalytical Chemistry 2023, 944, 117652.

(12) Cao, L.^*; Li, D.^* Zinc electrodes: Overview. 2023.

(13) Baker, J.; Cao, L.; Hwang, Y.^*; Wang, C.; Radermacher, R. Performance investigation of an electrochemical ammonia compressor stack. International Journal of Refrigeration 2023, 153, 67-77.

(14) Ma, L.; Pollard, T. P.; Zhang, Y.; Schroeder, M. A.; Ren, X.; Han, K. S.; Ding, M. S.; Cresce, A. V.; Atwater, T. B.; Mars, J. Cao, L.; … Xu, K.^* Ammonium enables reversible aqueous Zn battery chemistries by tailoring the interphase. One Earth 2022, 5 (4), 413-421.

(15) Deng, T.; Ji, X.; Zou, L.; Chiekezi, O.; Cao, L.; Fan, X.; Adebisi, T. R.; Chang, H.-J.; Wang, H.; Li, B.… Wang, C.^*; Lu, X.^* Interfacial-engineering-enabled practical low-temperature sodium metal battery. Nature Nanotechnology 2022, 17 (3), 269-277.

(16) Bai, P.; Ji, X.; Zhang, J.; Zhang, W.; Hou, S.; Su, H.; Li, M.; Deng, T.; Cao, L.; Liu, S. …Xu, Y.^*; Wang, C.^* Formation of LiF‐rich cathode‐electrolyte interphase by electrolyte reduction. Angewandte Chemie International Edition 2022, 61 (26), e202202731.

(17) Wang, C.^*; Hwang, Y.; Cao, L.; Baker, J. Electrochemical Ammonia Compression. In Electrochemical Society Meeting Abstracts 240, 2021; The Electrochemical Society, Inc.: pp 751-751.

(18) Li, D.^#; Cao, L.^#; Deng, T.; Liu, S.; Wang, C.^* Design of a solid electrolyte interphase for aqueous Zn batteries. Angewandte Chemie International Edition 2021, 60 (23), 13035-13041.

(19) Jin, T.; Ji, X.; Wang, P. F.; Zhu, K.; Zhang, J.; Cao, L.; Chen, L.; Cui, C.; Deng, T.; Liu, S. …Jiao, L.^*; Wang, C.^* High‐energy aqueous sodium‐ion batteries. Angewandte Chemie International Edition 2021, 133 (21), 12050-12055.

(20) Deng, T.^#; Cao, L.^#; He, X.; Li, A.-M.; Li, D.; Xu, J.; Liu, S.; Bai, P.; Jin, T.; Ma, L. …Wang, C.^* In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries. Chem 2021, 7 (11), 3052-3068.

(21) Cao, L.^#; Li, D.^#; Soto, F. A.^#; Ponce, V.; Zhang, B.; Ma, L.; Deng, T.; Seminario, J. M.; Hu, E.; Yang, X. Q.; …Balbuena, P.^*; Wang, C.^* Highly reversible aqueous zinc batteries enabled by Zincophilic–Zincophobic interfacial layers and interrupted hydrogen‐bond electrolytes. Angewandte Chemie International Edition 2021, 60 (34), 18845-18851.

(22) Cao, L.^#; Li, D.^#; Pollard, T.; Deng, T.; Zhang, B.; Yang, C.; Chen, L.; Vatamanu, J.; Hu, E.; Hourwitz, M. J. …Xu, K.^*; Borodin, O.^*; Wang, C.^* Fluorinated interphase enables reversible aqueous zinc battery chemistries. Nature nanotechnology 2021, 16 (8), 902-910.

(23) Sun, R.; Ji, X.; Luo, C.; Hou, S.; Hu, P.; Pu, X.; Cao, L.; Mai, L.; Wang, C.^* Water‐Pillared Sodium Vanadium Bronze Nanowires for Enhanced Rechargeable Magnesium Ion Storage. Small 2020, 16 (30), 2000741.

(24) Ma, L.; Schroeder, M. A.; Pollard, T. P.; Borodin, O.; Ding, M. S.; Sun, R.; Cao, L.; Ho, J.; Baker, D. R.; Wang, C.^* Critical factors dictating reversibility of the zinc metal anode. Energy & Environmental Materials 2020, 3 (4), 516-521.

(25) Deng, T.; Ji, X.; Zhao, Y.; Cao, L.; Li, S.; Hwang, S.; Luo, C.; Wang, P.; Jia, H.; Fan, X. …Wang, C.^*; Zhang, J.^* Tuning the anode–electrolyte interface chemistry for garnet‐based solid‐state Li metal batteries. Advanced Materials 2020, 32 (23), 2000030.

(26) Chen, L.^#; Cao, L.^#; Ji, X.; Hou, S.; Li, Q.; Chen, J.; Yang, C.; Eidson, N.; Wang, C.^* Enabling safe aqueous lithium ion open batteries by suppressing oxygen reduction reaction. Nature Communications 2020, 11 (1), 2638.

(27) Cao, L.^#; Li, D.^#; Hu, E.; Xu, J.; Deng, T.; Ma, L.; Wang, Y.; Yang, X.-Q.; Wang, C.^* Solvation structure design for aqueous Zn metal batteries. Journal of the American Chemical Society 2020, 142 (51), 21404-21409.

(28) Cao, L.^#; Li, D.^#; Deng, T.; Li, Q.; Wang, C.^* Hydrophobic organic‐electrolyte‐protected zinc anodes for aqueous zinc batteries. Angewandte Chemie International Edition 2020, 132 (43), 19454-19458.

(29) Deng, T.; Fan, X.; Cao, L.; Chen, J.; Hou, S.; Ji, X.; Chen, L.; Li, S.; Zhou, X.; Hu, E. …Wang, C.^* Designing in-situ-formed interphases enables highly reversible cobalt-free LiNiO2 cathode for Li-ion and Li-metal batteries. Joule 2019, 3 (10), 2550-2564.

(30) Tang, X.; Zeng, Y.; Cao, L.; Yang, L.; Wang, Z.; Fang, D.; Gao, Y.; Shao, Z.^*; Yi, B. Anchoring ultrafine Pt nanoparticles on the 3D hierarchical self-assembly of graphene/functionalized carbon black as a highly efficient oxygen reduction catalyst for PEMFCs. Journal of Materials Chemistry A 2018, 6 (31), 15074-15082.

(31) Zhang, H.; Zeng, Y.; Cao, L.; Yang, L.; Fang, D.; Yi, B.; Shao, Z.^* Enhanced electrocatalytic performance of ultrathin PtNi alloy nanowires for oxygen reduction reaction. Frontiers in Energy 2017, 11, 260-267.

(32) Cao, L.; Jiang, S.; Zhang, G.; Tang, X.; Qin, X.; Shao, Z.^*; Yi, B. Fabrication of a highly dispersed Pdcore@ Ptshell electrocatalyst for the oxygen reduction reaction. Chinese Journal of Catalysis 2017, 38 (7), 1196-1206.

(33) Cao, L.; Jiang, S.; Qin, X.; Shao, Z.^*; Yi, B. Preparation of monodispersed ultra-small PtCu alloy with remarkable electrocatalytic performance. In Electrochemical Society Meeting Abstracts 232, 2017; The Electrochemical Society, Inc.: pp 1524-1524.

(34) Zhang, G.; Lu, W.; Cao, L.; Qin, X.; Ding, F.; Tang, S.; Shao, Z.-G.^*; Yi, B. Large faceted Pd nanocrystals supported small Pt nanoparticles as highly durable electrocatalysts for oxygen reduction. Journal of Power Sources 2016, 326, 23-34.

(35) Jiang, S.; Yi, B.; Cao, L.; Song, W.; Zhao, Q.; Yu, H.; Shao, Z.^* Development of advanced catalytic layer based on vertically aligned conductive polymer arrays for thin-film fuel cell electrodes. Journal of Power Sources 2016, 329, 347-354.

(36) Cao, L.; Zhang, G.; Lu, W.; Qin, X.; Shao, Z.^*; Yi, B. Preparation of hollow PtCu nanoparticles as high-performance electrocatalysts for oxygen reduction reaction in the absence of a surfactant. RSC advances 2016, 6 (46), 39993-40001.

(37) Cao, L.; Zhang, G.; Jiang, S.; Tang, X.; Qin, X.; Guo, X.; Shao, Z.^*; Yi, B. Enhancing the oxygen reduction reaction performance by modifying the surface of platinum nanoparticles. ChemElectroChem 2016, 3 (2), 309-317.